yes everyone has a surname even in pokemon and brock also has one but it is not mentioned in the pokemon anime
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yes
You can catch a grass type Pokemon but catching mankey is the easiest because it appears a lot especially to the east of Pewter (where Brock is). Mankey has the advantage of being a fighting Pokemon which is super-effective against Brock's Pokemon.
Onix.
Brock sings several too many times to list.
your mkom
NO he cannot. only Your lead Pokemon can follow you.