NO he cannot. only Your lead Pokemon can follow you.
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You can catch a grass type Pokemon but catching mankey is the easiest because it appears a lot especially to the east of Pewter (where Brock is). Mankey has the advantage of being a fighting Pokemon which is super-effective against Brock's Pokemon.
In video games, the only version you can make your Pokemon follow you is in Pokemon yellow ( only pikachu), Pokemon heartgold, and Pokemon soulsilver
She had zero experience with pokemon, so when she met Ash, she decided to follow and learn from him and Brock across Sinnoh.
yes everyone has a surname even in pokemon and brock also has one but it is not mentioned in the pokemon anime
You cannot evolve Pikachu in Pokemon Yellow, unless you trade it to a red or blue version, and give it a thunderstone there. Once you get it back it will not follow you.