pekingese is not a real Pokemon so no!
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you either get a male and female pikachu and put them in the day care or you get a pikachu and a ditto.
Breed a female pikachu with any Pokemon from its breeding group or any pickachu with a ditto.
It can usually learn egg moves. They are moves they get from there mum and dad Pokemon such as volt tackle, which can be gained when giving a light orb to the father Pikachu before breeding.
You can only get Volt Tackle by breeding Pikachu or Raichu with the Light Ball item attached to them however 1 of them has to be a female Pikachu or Raichu so that they can lay a Pichu Egg that will know Volt Tackle when it hatches.
Volt tackle is not a TM. Volt tackle can only be tought by breeding. Get a Pikachu, It has to be a girl, and a light ball. (If your Pikachu wasn;t a part of the five persint holding one thief one off another and run far and hard) Make your female Pikachu hold the light ball and put it in the daycare with a male Pikachu or another breedable Pokemon (a male Pikachu will give you a faster egg.) And when your Pichu hatches it will know Volt Tackle.