you either get a male and female pikachu and put them in the day care or you get a pikachu and a ditto.
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you go to the trophy garden behind the Pokemon mansion.
pikachu then pikachu evolves with a thunderstone to get raichu
Breed a female pikachu with any Pokemon from its breeding group or any pickachu with a ditto.
It is really hard to get one. On Pokemon Platinum you need to find PIchu/Pikachu and catch it or use thief and if your lucky enough it will be holding a light ball. I
You can only get Volt Tackle by breeding Pikachu or Raichu with the Light Ball item attached to them however 1 of them has to be a female Pikachu or Raichu so that they can lay a Pichu Egg that will know Volt Tackle when it hatches.