you have to get the move tutor to teach it to him by giving him a heart scale.
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Breed the scyther that you want and when it's level one, trade it holding the metal coat. After the trade it will evolve in Scizor. It will then learn bullet punch. I also think a move tutor can teach bullet punch to Scizor.
level 1 it learns bullet punch
Darumaka learn fire punch at level 22Hope I helped
It doesn't learn Mach Punch.
He doesnt learn ice punch