episode 125 of shippuden
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It's after the ending credits in episode 25 of naruto shippuden.
Deidara is in the first 30 shippuden episodes. The Gaara retrieval arc is all about Deidara, Sasori, and Gaara. Deidara loses both his arms in these episodes when fighting Kakashi.
Naruto Shippuden Episode 99: Raging-Tailed Beast.
When he fights Deidara shippuden 32 I believe
The episode title is Aesthetics of an Instant, it's episode number is Thirty in Naruto Shippuden.