When he fights Deidara shippuden 32 I believe
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Shippuden Episode 43.
Minato appeared in Naruto Shippuuden Episode 168 when Naruto sprouted the ninth tail during the fight with Pain.
after the chunin exam To be a little more specific, Naruto encounters Gaara episode 77 Light vs. Dark: The Two Faces of Garra. They don't start fighting until, 78-80, naruto's Ninja Handbook.
the episode is uknown during naruto shippudin tunada kakashi and jarya and yamoto discus about how dedly the nine tails are and that the max that naruto can control is 3 tails and if he reaches 9 tails he will die so the awnser is when thay have the discusion jairiayahas a flash back i don't know what the epp. is though and the max ive seen naruto go is 6 tails
naruto dad dies when sealing the nine tails in naruto when he was a baby and in the shippuden episode naruto's dad is just a spirt in naruto's body gurding the seal so he can't stay with naruto forever like that and naruto came out the nine tail chamber inside him but his dad's spirt stayed there.