she is kidnapped in episode 140
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orihime ends up with chad
There isn't any technical romance in bleach (you could count orihime's love for ichigo as romance I suppose, however they're not together). However I think Ishida might like her by the way he tends to look at her and worry about her.
REALLY REALLY BIG LIKE 38 F!
i think he is 22 now and he is not kidnapped anymore
Luppi dies when Aizen orders Orihime to heal Grimmjow's left arm and after she does Grimmjow tells her to heal his scarred back where his 6 tattoo was and the tattoo comes back. Luppi asks what he's doing and Grimmjow stabbs his hand into Luppi's heart and says 'goodbye former 6' nd yea dunno which ep. its 1 or 2 episodes after Orihime gets kidnapped