He doesn't. Super Saiyan 5 doesn't exist.
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214 vegeta,s pride
What episode does goku turn super saiyan 3?Cut American version episode 230. Super Saiyan 3?!Uncut American version episode 245. Super Saiyan 3?!Japanese episode 245. Super Saiyan 3?!First aired: 9/26/2002
In the Majin Buu Saga after Buu was resurrected. When Vegeta was in the heavens after he died, he saw Goku go SS3 and accused Goku of mocking him with that transformation. In case you were looking for the episode number it was episode 245
He first transforms in the episode "Upgrade to Super Saiyan", which is episode 129. Or 114 of the cut version. So far, that episode of Dragonball Z Kai has not come out.
the year he fought frieza