Sadly, Duck and Fakir never kiss in the show. But if you want to see a really romantic pas de deux with the two of them I suggest episode 25.
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Despite what people may think the scene when Ahiru and Fakir kiss is not an episode. Rather, it is a promotional trailer for the series. If you search "Princess Tutu Promo" or "Princess Tutu Promotional Trailer" you'll find it easily.
I'm not sure what exactly you mean by "get together", but in the end Fakir promises Duck that he will stay by her side forever, even after she turns back into a duck. Duck has no choice but to turn back into a duck and at the very end of the series it shows Duck swimming in the lake and Fakir sitting on the dock fishing and writing a story, because he kept his promise. You are to believe whatever you want to happen after that.
They kiss in episode 16 and episode 33
they dont actually kiss but in episode 4 its like a kiss he has to kiss her to get medicine in her mouth and in episode 8 he kisses her on the nose and episode 24 he kisses her on the neck
There is no first episode that Naruto and Hinata kiss because they don't kiss.