The formic acid is a weak acid.
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In order to have an effective buffer, one needs to have a weak acid or a weak base, and the salt (conjugate) of that weak acid or weak base. Examples would be :weak acid/conjugate base: acetic acid/sodium acetateweak base/conjugate acid: ammonia/ammonium chloride
HF is a weak acid.
If you are titrating a base, using a weak acid as titrant would lead to the formation of a buffer as you added the weak acid. The weak acid would react with the base to form the salt of the weak acid + water, and this would buffer any changes in pH, thus making the titration meaningless.
I think it is neutral
Dissolved carbon dioxide in water (carbonic acid) is weak acid.