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Female Snorunt to Froslass, or male Kirlia to Gallade. The use for this stone is very restricted.
In HG SS it doesn't evlove anything But it does evlove a male kirlia into a gallade and a female snorunt into a frosslass
Dusk stones/shiny stones/ dawn stones/and oval stones are items that make certain Pokemon evolve. You can get A dusk stone in the galatic building in veilstone city. you evolve happiny by giveing it a oval stone and lvling it up murkrow evolves with dusk stone you evolve Roselia by using a shiny stone you can evolve togetic with a shiny stone
most of the stones (moon stone, thunder stone, leaf stone, sun stone, dawn stone, dusk stone, oval stone, shiny stone, ....etc.....) make Pokemon evolve. However, the everstone prevent the holder from evolving.
I'm not 100% sure if all of these are in Pokemon Pearl, but the ones that evolve with a Dusk Stone are... Murkrow, which will evolve into Honchkrow. Misdreavus, which will evolve into Mismagius. Lampent, which will evolve into Chandelure. (I'm almost positive this one is only in Black/White.)
A Dawn Stone is used to evolve a male Kirlia into a Gallade and a female Snorunt into a Froslass.
You can evolve Snorunt into two different pokemon. If you want to have a Glalie level it to Lv 42. If you have a female Snorunt you can also evolve it to Froslass, Just give her a dawn stone. If you don´t have a dawn stone you can find one at route 225.