Yes, Nidoking is capable of learning Surf (HM03).
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Yes
there are a lot of Pokemon that can learn surf but mostly water type Pokemon can learn surf but did you know that snorelax and rydon can lean surf
YES! It is a water Pokemon and can learn to surf.
Get the HM Surf then teach it to a pokemon.
Manaphy cannot learn Surf but it can be taught it via the Surf HM.