No; as DBZ Kai is an anime based only on canon plot and characters, Broly, a non-canon (fan-created) character will not appear.
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Vic Mignogna(he also plays Broly and Burter)
Dragon Ball, Dragon Ball Z, Dragon Ball GT, Dragon Ball Z Kai, Dragon Ball Kai, Dragon Ball Abridged. V&Y LOVER (VEGETA & YAMCHA)
nothing this is the final series in dragon ball. :( What?? This is wrong.There is much after the Kai story. Dragon Ball Z Kai is just a re-edit of Dragon Ball Z Season 1 - 6.The quick answer is "Dragon Ball Z - Season 7-9" is after Kai. Then after that is Dragon Ball GT.
There are 4, including the revised version of Dragon Ball Z (Dragon Ball Kai). There are 3 series: Dragon Ball, Dragon Ball Z, and Dragon Ball GT. Dragon Ball has 153 episodes that ran as 3 seasons in Japan (1986-1989). Dragon Ball Z has 291 episodes that ran in 7 seasons (1989-1996). Dragon Ball GT has 64 episodes that ran as one extended season (Jan. 1986 to Nov. 1987). The refurbished and extended Dragon Ball Z (Kai or Z Kai) aired from 2009 to 2011. Further versions were not expected to air on Japanese TV, but could appear in overseas markets.
Dragon Ball Z Kai episode 47