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The only Pokémon that can naturally learn Waterfall in Pokémon Black is Goldeen and Seaking however Pokémon that are capable of being taught it via the HM would include Squirtle, Psyduck, Poliwag, Tentacool, Seel, Horsea, Staryu, Gyarados, Lapras, Vaporeon, Omanyte, Kabuto, Dratini, Mew, Totodile, Chinchou, Azurill, Wooper, Qwilfish, Remoraid, Mantyke, Suicune, Lugia, Mudkip, Lombre, Carvanha, Wailmer, Barboach, Corphish, Feebas, Spheal, Clamperl, Relicanth, Luvdisc, Latias, Latios, Kyogre, Rayquaza, Piplup, Bibarel, Buizel, Gastrodon, Finneon, Phione, Manaphy, Arceus, Oshawott, Panpour, Basculin, Tirtouga, Frillish and Alomomola.

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Q: Which pokemon can learn waterfall on Pokemon Black?
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