The only Pokémon that can naturally learn Waterfall in Pokémon Black is Goldeen and Seaking however Pokémon that are capable of being taught it via the HM would include Squirtle, Psyduck, Poliwag, Tentacool, Seel, Horsea, Staryu, Gyarados, Lapras, Vaporeon, Omanyte, Kabuto, Dratini, Mew, Totodile, Chinchou, Azurill, Wooper, Qwilfish, Remoraid, Mantyke, Suicune, Lugia, Mudkip, Lombre, Carvanha, Wailmer, Barboach, Corphish, Feebas, Spheal, Clamperl, Relicanth, Luvdisc, Latias, Latios, Kyogre, Rayquaza, Piplup, Bibarel, Buizel, Gastrodon, Finneon, Phione, Manaphy, Arceus, Oshawott, Panpour, Basculin, Tirtouga, Frillish and Alomomola.
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almost all of the water type Pokemon can learn and use waterfall
wailmer
Most water Pokemon will learn waterfall i believe. For certain if you have PIPLUP, TENATACOOL, or TENTACRUEL, it will learn Waterfall. Hope I Helped!
squirtlewarturtleblastoisepsyduckgolduckpoliwagpoliwhirlpoliwrathtentacooltentacruelseeldewgonghorseaseadragoldeen seakingstaryustarmiegyradoselaprasvaporeonomanyteomasterkabutokabutopsmewchinchoulanturnmarillazumarillpolitoedquagsireslowkingqwillfishremoraidoctillareekingdrasuicune My Lapras and Gyrados Know the move waterfall
Most water type Pokemon can learn the move Waterfall.