It depends, its not about the deck but the strategy you use plus you can make your own deck with your own ultimate combos! =)
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It depends on what type of starter deck e.g. Yugioh 5ds, Yugioh GX, Yugioh!
He plays an infernity deck. Go on yugioh wikia and search infernity
You can obtain Junk Warrior by getting the structure deck which it's in. It's in the Yugioh 5ds Starter Deck.