Ash battles Gardenia in the episode: The Grass Menagerie
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Ash battles Richie in episode 81: Friend and Foe Alike.
The Pokémon episode in which Ash's Charizard battles Articuno is "The Symbol Life" and its overall episode number is Episode 413.
there are many episodes that he battles pual.i think episode 54,92,and 106. I THINK.
Ash's Chimchar evolves into a Monferno in Pokémon DP Galactic Battles episode 27. It is titled "Evolving Strategies". its ep 601
Yes, in episode 600 when Ash battles against Paul the 2nd part of their battle will be aired on youtube on June 18th (only in Japanese)