Slakoth
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u can teach vulpix dig.
Relicanth are found on the seafloor of the ocean(rare). You must have a Pokemon that learns dive though.
level 33, then learns waterfall at 41
You can give specific Pokemon TM28 Dig that you get from that town with all those ashes, and I know Nincada learns it naturally if you don't evolve it (I think it learns it Level 45).
I only know 3 moves that makes Pokemon fall asleep. GrassWhistle - Roselia learns it by level up Yawn - Dunsparce learns it by level up Hypnosis - Drowsee knows it when captured in Pokemon Heart gold And Soul silver.