deoxys attack form has the most, can have up to 504 special attack
mewtwo has the second most at 447 sp atk
darkrai and alakazam are tied for third, at 405
And i believe gengar has the fourth most, at 394
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Rampardos has the highest attack.
It depends on what you mean.The Pokemon with the highest total stats attainable in Emerald is Mewtwo, who also has the Special Attack record.The Pokemon with the highest HP stat is Blissey.The Pokemon with the highest Attack is Slaking.The Pokemon with the highest Defence is Shuckle. Shuckle also has the highest Special Defense.The Pokemon with the highest Speed is Ninjask.Another AnswerThe highest total base stats currently obtainable in the game is Rayquaza's. Groudon and Kyogre are second highest, but are also equal to Slaking. It's stats are probably this high because of it's Truant ability - it is inactive every other turn.So Rayquaza has the highest stats, but Slaking is the highest non-legendary.
deoxys in attack form
Special Attack determines the amount of damage dealt from a move that is in the Special category of attacks. An example of a special attack would be Bubblebeam. If an attack is in the special category, it means that it is an attack in which your Pokemon's body does not make physical contact with the other Pokemon. Example: Tackle would be a physical attack, because your Pokemon charges at your opponent's Pokemon, which makes them physically contact, while Bubblebeam is projected from a Pokemon's mouth, so your Pokemon does not physically touch your opponent's Pokemon. Special Defense deals with how much protection you get from Special category moves.
Special attack cause its a electric type.