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Staraptor can't learn Heat Wave... Only Fire-Type Pokemon can.
Charizard learns Heat Wave at start in Pokemon FireRed. In Generation IV, Charizard learns it at level 59. In Platinum, HeartGold and SoulSilver, Charizard can also learn Heat Wave by move tutor.
charazard better moves more attack easier level up + Infernape has really low stats except attack and speed. 'Zard's stats are better overall. Plus Charizard learns heat wave which is a really useful move.
So far, only three events have been released in Japan. Those three are the Secret Key (in which you gain the ability to turn Rotom into Frost, Heat, Wash, Fan, and Mow Rotom), the Member's Card (in which you gain the ability to capture Darkrai), and Oak's Letter (in which you gain the ability to capture Shaymin). Otherwise, I highly doubt there will be anymore events, for those seem to be the only Pokemon in the Pokemon Diamond, Pearl, and Platinum Version generations that are practically impossible to get without ending up with a hacked version of the Pokemon.
I dont think there is a move called heat wave in the game firered.AnswerHeat Wave is a move in Pokemon FireRed. However, it cannot be taught to a Pokemon via a TM or move tutor. Pokemon must reach a certain level which they learn Heat Wave naturally. The Pokemon who can learn Heat Wave include: Charizard, Moltres (level 73) and Torkoal (level 46). Through breeding, Vulpix, Growlithe and Slugma may also learn Heat Wave. get 2 tinymushrooms from paras and go to island 2 and there is a guy in a house that teaches heat wave to charizard