The School Kid Alan at Route 36 will give you a call on Wednesdays and give you the Firestone if you meet him. Bill's grandfather who lives in Bill's house near Cerulean City will give you a Firestone if you show him a Growlithe or Vulpux. You can also get them at the Pokeathlon Dome on Tuesdays, Thursdays, and Sundays in exchange for 2500 points at the prize counter.
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VulpixGrowlitheEevee
you need to give vulpix a fire stone
You have to catch a Growlithe, then give it a Fire Stone. It evolves.
In order of how he wants to see them (based on Heart Gold and Soul Silver): Gold/Heart Gold: Oddish - Leaf Stone Growlithe - Fire Stone Pichu - Thunderstone Jigglypuff - Everstone Marill - Water Stone Silver/Soul Silver: Lickitung - Everstone Oddish - Leaf Stone Staryu - Water Stone Vulpix - Fire Stone Pichu - Thunderstone
You have to get his phone number and then alittle later he will call you and say to come to him he has a present and it will be the fire stone!!HOPE THIS HELPS ALOT