you need to give vulpix a fire stone
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Vulpix cannot evolve by leveling up. You will need a firestone so that it can evolve to become Ninetales.
Okay, you need to use a fire stone on it, but remember this carefully: It will only work on a female Vulpix, not a male Vulpix.
You can't catch vulpix in Heart Gold, though you can catch it in Soul Silver. On the small route 37, Below Ecruteak City, you can find: ~Heart Gold = growlithe ~Soul Silver = vulpix (they both evolve using a fire stone)
Level 30.
level 36