Go to celadon city and find the cafeteria its one of the houses on the bottom talk to the guy at the top left and he will give you his coin case.
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you find them underground
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.
Go to celadon city and in the southeast corner of the city (east of the Pokemon center)and there are three accesable homes. Go in the very left of the three and when you walk in there will be a man in the northwest corner of the room and if you talk to him he will give it to you for FREE!!!!!!
In the game Pokemon ruby destiny