TM22 is Solarbeam. You get it at the Pokemon Mansion.
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Go to Veilstone City, enter the Department Shop. There you can buy TM22 (Solar Beam) ;)
Solarbeam is in the Safari Zone.
You can find Tm22 Solarbeam in the Goldenrod City Department Store. (TM Corner) Note: Sold at Price of 3,000.
In Pokemon firered you can't, but in Pokemon leafgreen you can get it then trade it to Pokemon firered.
To get Pokemon firered on PC download a vba and Pokemon firered ROM