If you are holding the guitar like you would when you are playing, then the sync button is on the right side, right next to the headset input and strap connection.
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you press the sync button on the wireless guitar and on the xbox 360
Sync, like to connect a wireless guitar to the system? There's a small button at the bottom of it, near the nub for the guitar strap. Hold that in, and hold in the small button next to the memory card slot on the xbox till they sync up.
hit the sync button on the wireless adapter and the sync button on the guitar
The sync button is the big X in the middle of the controller. It has a green X with a silver circle. All you have to do is push the button and wait.
this answer is for xbox 360 turn your xbox 360 on hold down the sync button on your xbox 360 hold down th sync button of the guitar AT THE SAME TIME AS HOLDING DOWN THE SYNC BUTTON ON YOUR XBOX 360 when both the lights on your xbox 360 and your guitar are flashing, then release BOTH buttons. the guitar and console should now be synced up with each other. hope this helps ;P