Well it really depends on what you want to catch. I like to fish with a super rod at the safari zone because you can somtimes catch a dratini and you may be able to catch dragonair too but im not sure.
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Rainy places
In Fushia City you can get a Good Rod. Fish somewhere.
You fish for it in the town the third gymleader is with a super rod.
Fishing guide
Fish for it in the river by Fortree City using the best rod that you have.