elite 4 lucian has one on his team route 212 south - Scientist Shaun route 214 - Psychic Mitchell you can get one by trading a kadabra with some one.
other trainers in victory road may have one they may not but he is the main one.
hope that i helped!
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evolve alakazam from kadabra in level 100. just kiding at level 45
Elite 4 Lucian
Kadabra evolves to alakazam by trading it though it won't evolve if you migrate it to diamond from firered or leafgreen so what do you do? Get a kadabra in diamond trade it to a pearl version take it back and it will be a alakazam.
by traveling by walking not flying
The only way Alakazam can learn Fire Punch is through a Move Tutor on Pokemon Emerald Version.