First, you must have beaten the Elite 4 and have obtained the National Pokedex. Then, insert FireRed into your DS and you will find Elekid at Route 205 or Valley Windworks.
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Sorry if you don't have Firered then u can't get it
Catch the evolved form of Elekid, they sometimes have one.
The electrizer can be found held by wild Elekid (5% of the time). Elekid can be found at the Valley Windworks if you have Pokemon FireRed in the GBA slot of your DS.
1. use pokeradar in 205, there is a 7% chance to find elekid 2. breed a electrabuzz with ditto the egg will be elekid 3. trade it with someone
in route 205 use pokeradar there is a 7% chance to find elekid and a 5% chance of getting a electrizer