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Catch the evolved form of Elekid, they sometimes have one.

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Q: How do you get an electrizier in Pokemon pearl?
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There is one in Cerulean Cave.


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After you obtain the National Pokedex, Insert the FireRed cartridge into your DS and go to route 205 or the valley windworks. You will have a chance of catching a wild elekid with an electrizer as its held item. You can also find one in Platinum on the ground, which you can give to a Pokemon to hold and then trade.


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