there is no scanner on fire red/leaf green. Only on ruby, sapphire, emerald
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Chimchar is not obtainable in Pokemon FireRed or LeafGreen. The game it is in (Such as; Pokemon Pearl, Diamond, and Platinum.) is unable to connect to FireRed, unless migrating Pokemon from it, but Pokemon cannot be transferred into the Gameboy Advance games.
You can't find Turtwig on FireRed because he is in a different generation of the game. He is only found in Diamond and Pearl.
You can't find manaphy in firered because it didn't exist when the game was made if you want it you will need to play a game where it does exist in like diamond and pearl.
No you can't. Since the DS and Gameboy Advanced is not backwards compatible, you can't send a Piplup (from a Diamond, Pearl or Platinum) game to Pokemon FireRed.
you cannot get him on leafgreen or firered you have to trade from emerald or a gamecube Pokemon game like xd