you cannot get him on leafgreen or firered you have to trade from emerald or a gamecube Pokemon game like xd
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You can find Smeargle in route 212 using the Poke Radar.
you find him in the ruins of alph by weeds and you can find smeargle on there same thing on Pokemon heart gold (natu evolves at level 25)(smeargle no evolvetion)
Piplup does not exist in Pokemon LeafGreen or FireRed.
You cannot catch houndour in Pokemon leafgreen either get one from Pokemon emerald or Pokemon colosseum.
That item doesn't exist in leafgreen.