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I have Pokemon soul silver and this works for me so it should work in heart gold. Since a light ball is rare ( they are held by picachu's but there is only 5% chance) , so there is another way. If you haven't beaten the elite four and you can't go to mount silver, don't bother to try to do what I'm about to tell you, just keep catching picachus. but if you can go in mount silver keep reading. Ok then take a high level Pokemon that knows thief. Make sure it has no items on it. Put it as your first Pokemon. Then go to mount silver, and go to the top and battle Red. when his picachu comes use thief on him. You will take his light ball. Then win or lose and there you go! a light balll ! you can repeat this as many times.

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Q: Where do you find a light ball in Pokemon heartgold?
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