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You haven't made it far then. You can catch old pokemon. Yes, you can catch Riolu in the challenger's cave after you beat the elite 4. He's rare though.

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Q: Where do you catch a Riolu in Pokemon Black and White?
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Related questions

Can you catch Riolu in Pokemon white?

Yes it is possible.

Where can you find a Lucario on Pokemon Black?

You Cannot catch lucario on pokemon black the only Way is to trade him or catch a riolu.

Where can you catch a shiny riolu in Pokemon Black 2?

Anywhere that you can catch Riolu. Shiny Pokemon can appear anywhere and anytime; with a 1/8192 chance of one appearing.

Where do you catch a Riolu in Pokemon black and white and the season?

I think that the season is any season, and you catch him in the Challenger's Cave on Route 9. Also, Riolu is a Pokemon that evolves by friendliness so give the soothe bell and level him up and DON'T LOSE!! That makes a Pokemon less friendly.

Where do you catch riolu in pokemon black?

You can catch Riolu in Challangers cave. You can't enter challangers cave till you have beaten the eliet four at least once.

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Catch a Riolu and evolve Riolu.

Can you catch Rufflet in Pokemon Black?

No, it is exclusive to Pokemon White. Where you would catch Rufflet in White, you catch Vullaby in Black.

What legendary pokemon can you catch in Pokemon Black but not white?

In Pokemon black you catch RESHIRAM and TORNADUS In Pokemon white you catch ZEKROM and THUNDERUS Sources : myself

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You can't catch it in Black, but you can catch it in White. In the White Forest.

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Where do you catch rufflet in Pokemon Black?

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