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You have to talk to the lady furthest away from the entrance when you go into a pokemart. It's only in some towns, like Saffron City and Azalea.
go to the safari zone and talk to the people in the stalls its one of the and u can buy the balls u want ........talk to all of them because i dunno which person it is

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Q: Where do you buy Dusk Balls from in Pokemon SoulSilver?
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