The safari zone.
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Psyduck is in firered not leafgreen you can find it using a good or super rod in the safari zone.
You have to trade it in from another game.Seafoam islandsPsyduck is only in firered trade one to leafgreen.You can get psyduck by throwing a poke ball at him that will let you have him.
some Kanto city in the water i think. But for sure in the water in the Safari Zone. ANSWER : Psyduck cannot be found in Leaf Green, only in Fire Red.
you cant
Dive is not an HM in leafgreen you can't get it unless you trade a Pokemon that knows Dive from ruby or sapphire or emerald but it will not work in leafgreen unless your in battle.