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A good way you can do it is get an aipom from the honey tree, then evolve it into an ambipom.

either evolve the aipom or go to pastoria city at a certain day ( idk exactly when ) and theres a clown named lee in the Pokemon center, he has an ambipom lv 50

Another way to see one would be to battle Ace Trainer Blake on Route 216 who is just before the cave.
you can't see ambipom but you can catch aipoms by slathering honey on trees and evolve them

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Q: Where can you see an Ambipom on Pokemon Platinum?
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