You can't. you have to get staryu first
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The Pokemon that evolve using a water stone: Eevee Starmie Lombre Poliwhirl, too...
no you cannot find starmie in fire red you can trade starmie from Pokemon leaf green
# Starmie and staryu
yes but there weak against grass pokemon
its not an emerald its RAYQUAZA the main legendary Pokemon in Pokemon emerald.