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yes you can. but if you have Pokemon soulsilver, the first encounter will be a lugia and vice versa for ho-oh.
If you want a Lugia egg, first get the actual one. Then get a Ditto and put the actual Lugia and the Ditto in the day care (located south of Goldenrod City). Wait for them to have an egg and you'll have a Lugia egg.
You get a Pokemon that's effective against Phychic or Flying. Personally, I wouldn't defeat Lugia...
Lugia learns Sky Attack at level 99.
Lugia doesn't learn psychic in Pokemon soul silver on his own. However, you can easily teach Lugia psychic if you have the move in your possession.