You cannot catch Shaymin in Pokemon Black or White. You'll need to trade for it from the GTS or transfer it from the Transfer Lab.
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Yes you can catch Reshiram in Pokemon black and you can catch zekrom in Pokemon white hope it helped.
u cant.
You can catch Zekrom in Pokemon White and Reshiram in Pokemon Black. They are version exclusive legendaries so the only ways you could get both is through hacks or trading with someone.
Shaymin, Darkrai, and Arceus are event-only Pokemon which an Action Replay is required to catch them today or you can trade for them with a close friend.
The Pokemon Victini, does not exist in any version made before Pokemon Black and White. Since it was released to catch in 2010(Japan) and 2011 (other places) it won't be able to caught in any other version before Black and White. Unless they made another event where you can catch Victini in other versions you could not catch it.