Shaymin, Darkrai, and Arceus are event-only Pokemon which an Action Replay is required to catch them today or you can trade for them with a close friend.
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Shaymin, and 463 is Arceus
You have to either go to an event for them (check the Pokemon main site often for event Pokemon), get them from someone who went to the events, or hack for them.
I don't think you can. But if you buy an action replay then you can get codes to get Shaymin Darkrai any Pokemon you name you can get. I have 7 arceus 9 darkrai and 2 shaymin. You can get action replays from walmart target toysrus or something like that.
A rare Pokemon you can get by going to an event at places such as Gamestop and Toys R Us. Some examples are Arceus, Darkrai, Shaymin, and Shiny Pichu.
Arceus, Darkrai, and Shaymin P.S. in a new Pokemon (not out yet) Platinum, Shaymin Evolves. so does Giratina Can get REGIGIGAS and other event Pokemon like darkrai online at http://cgi.eBay.co.UK/ws/eBayISAPI.dll?ViewItem&item=140308748984 other event Pokemon on there aswell check the other items