YOU FIND IT IN FUSCHIA CITY NEXT TO THE WARDEN'S HOUSE
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Use a good rod in the safari zone.
In Fushia City you can get a Good Rod. Fish somewhere.
If you mean the old version, Pokemon Red, and not Pokemon Firered, then the only place that I can think of that have tons of fire Pokemon is the mansion on Cinnabar island. Go inside and walk around. You should find a lot of Ponyta and Vulpix, if you're playing Pokemon Blue, but if you're playing Pokemon Red, you'll more than likely find Ponyta and probably Growlithe. I'm not sure if you can find Vulpix in Pokemon Red or not. But, that's where you will find a lot of GOOD fire Pokemon. And, of course, Moltres is hidden away in Victory Road.
I think Exeggutor is.
No there is not.