Use a good rod in the safari zone.
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some Kanto city in the water i think. But for sure in the water in the Safari Zone. ANSWER : Psyduck cannot be found in Leaf Green, only in Fire Red.
in leaf green you cant find ekans, arbok, oddish, gloom, vileplume, psyduck, golduck, growlithe, arcanine, shellder, cloyster, scyther, and electobuzz but you can trade them from fire red.
No there is not.
you can not find him not 1 persent
You can't find a Vulpix in Pokemon FireRed version. That pokemon is version-exclusive to Pokemon LeafGreen.