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At level 22 in Diamond and Pearl and level 18 in Platinum/HeartGold/SoulSilver.
However, if you evolve it into Prinplup first, it is at level 24 for Diamond and Pearl and level 19 for Platinum/HeartGold/SoulSilver.
Also, there's no reason to use a TM for Bubble Beam when you can teach it much more powerful attacks like Surf later on.
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What moves can Piplup learn?
Piplup learns moves such as Growl, Bubble, Water Sport, Peck, Bide, Bubblebeam, Fury Attack, Brine, Whirlpool, Mist, Drill Pick and Hydro Pump.
When does wartortle learn bubblebeam?
Wartortle doesn't learn Bubble Beam naturally, but you can teach it with TM11 at any time.
When does piplup learn peck?
Piplup learns Peck at level 15
What moves does Blastoise learn?
Hydro pump, Strength, Skull bash, Surf, Subbmishion, Sesmic toss, Water gun, Bubble beam, Bubble, Withdraw, Mega punch
What level does rattata learn bubble?
rattata does not learn bubble at all, there isn't even a TM for bubble
