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Houndoom cannot learn thunder fang by leveling up. He can only learn thunder fang is when you breed a Houndoom and a pokemon that can learn thunder fang example ( Luxray )
houndoom learns flamethrower at level 50.
Houndoom learns Flamethrower at lvl 48.
Blastoise never learns Crunch. Blastoise does not learn Crunch, but it does learn Bite. This is when it is a Wartortle (or Squirtle) and is on level 16. If you have a Blastoise on level 16 (which is not really possible), it will learn Crunch.
Yes.