houndoom learns flamethrower at level 50.
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In order to teach Houndoom the move Thunder Fang you need to find the Move Reminder NPC. The Move Reminder NPC can teach Pokemon moves they previously learned or have hidden for one Heart Scale. One of the hidden moves Houndoom knows is Thunder Fang.
Houndoom cannot learn thunder fang by leveling up. He can only learn thunder fang is when you breed a Houndoom and a pokemon that can learn thunder fang example ( Luxray )
Houndoom learns Flamethrower at lvl 48.
Yes.
In Platinum version Houndoom learns Flamethrower at level 48. in diamond and pearl Houndoom also learns it at level 48.