If you breed a Chikorita, Bayleef or Meganium the hatched Chikorita should know Vine Whip.
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level 13
weepinbell learns vine whip sleep powder poison powder toxic
Here are some moves it can learn and will learn: Sludge bomb, Leech seed, Razor leaf, Vine whip, Hyper beam, Earthquake, Frenzy plant, Solarbeam, Giga drain, Mega drain, Body slam, Toxic and many more such as Sleep powder, Poison powder, Stun spore.
Vileplume, Paras, Parasect, Chikorita, Bayleef, Meganium, Roselia and Shaymin all learn Aromatherapy via level up in Diamond/Pearl.
Ash found his Chikorita in the episode that was titled "The Chikorita Rescue" however other Chikorita he has found is Casey's Chikorita who first appeared in the episode that was titled "The Double Trouble Header" and Lyra's Chikorita who first appeared in the episode that was titled "An Egg Scramble."