Ash found his Chikorita in the episode that was titled "The Chikorita Rescue" however other Chikorita he has found is Casey's Chikorita who first appeared in the episode that was titled "The Double Trouble Header" and Lyra's Chikorita who first appeared in the episode that was titled "An Egg Scramble."
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Ash's Chikorita evolved into Bayleef in the episode titled "Current Events."
Ah, what a happy little question! Chikorita evolves into Bayleef in the episode called "Current Events" in the Johto League Champions season. Just like how our paintings evolve with each brushstroke, Ash's Chikorita blossomed into a beautiful Bayleef on its journey.
season 3 ep 10.
the final episode
Chikorita / Bayleef actually hated as at first. But then started to have a crush on him after saving it. If you ever have any questions about Pokemon you just let me know!