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Ash got Charizard in episode 11
Ash battles Gardenia in the episode: The Grass Menagerie
Ash battled Norman in the episode "Balance of Power."
Ash found his Chikorita in the episode that was titled "The Chikorita Rescue" however other Chikorita he has found is Casey's Chikorita who first appeared in the episode that was titled "The Double Trouble Header" and Lyra's Chikorita who first appeared in the episode that was titled "An Egg Scramble."
The episode in which Ash meets Paul is the episode that is titled "When Pokémon Worlds Collide," it is the 3rd episode in the Sinnoh region and its overall episode number is Episode 471.