At route 216 just by the exit of mount cornet there is an ace trainer who used an ambipom. Also, if you haven't found a Porygon-2 yet, he uses one of them too
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there is a cool girl trainer in victory road who has one
there is a clown in one of the poke centers with ambipom
an ace trainer on route 216 or a clown in a Pokemon center.Goood luck!
An ace trainer on route 216 has an ambipom The trainers name is blake, he is the first trainer you will come across as you enter the route, if you head straight ahead he can be found facing away from the north wall so you have to pass his line of sight to advance without going to the upper level. He is armed with two pokemon: a level 39 ambipom and a level 40 porygon2 so be armed with fighting moves if you are of a similar level.
The trainer on Route 209 has Cleffa in Pokemon Platinum. Cleffa is a fairy type Pokemon and can evolve into Clefairy.