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There is a trainer with Masquerain in Pokémon Emerald, however, he doesn't use it until you're battling him for the 2nd time using the PokeNav. You'll know you've challenged him enough when his Surskits are level 34. The trainer is Bug Maniac Jeffrey and can be found on Route 120.

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Q: What trainer has a masquerain in Pokemon emerald?
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